Chm 531 (Summer 2022) 5. Provide the reagents and conditions needed to carry out the following transformations to afford

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Chm 531 Summer 2022 5 Provide The Reagents And Conditions Needed To Carry Out The Following Transformations To Afford 1 (43.25 KiB) Viewed 10 times

Chm 531 (Summer 2022) 5. Provide the reagents and conditions needed to carry out the following transformations to afford the product shown as the MAJOR product. More than one step may be necessary. (16 points, 4 each) ALCOHOL COMPOUND 8 6. When an alcohol containing compound and a thiol containing compound are subjected to hydration conditions both reactions give a pair of cyclic and aliphatic products. Interestingly, when the thiol compound is reacted with HCI/H₂O a greater yield of the cyclic products are obtained in comparison to when the alcohol compound is reacted with HCI/H₂S. Furthermore, more aliphatic products are obtained from the hydrate reaction upon the alcohol compound than the thiol compound. In the space provided, give a chemical rationale as to why this is. (10 points) Cycle Products Cycle Products trans-hept-5-en-2- на H₂S & OH ADPS) SH D (14%) CI (20%) (19%) Alphetic Product THEOL COMPOUND SH trans-hept-6-ene-2-hid на H₂O SH A (44%) OH HO, - "X D(%) SH B (32%) (9%) Alphatic Products OH