The expectation values of radial functions for Hydrogen-like atoms can be computed using a specific equation, known as K

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The Expectation Values Of Radial Functions For Hydrogen Like Atoms Can Be Computed Using A Specific Equation Known As K 1 (24.67 KiB) Viewed 44 times

The expectation values of radial functions for Hydrogen-like atoms can be computed using a specific equation, known as Kramer's relation: k+1 ark 6772() – (2k + 1)a(k-1) + 4** [(26 + 1)2 – k?] (-6-2) = 0, k) (+ pk n2 where a = n/uZe and (mk) = (nlm|rk|nlm), etc. = = 1 (a) Use (4) to compute (r) for k=-1, k = 1, and k = 2. - (b) Use the fact that (r-2) = 1/a’n’ (l+1/2) to compute (r-3).