[9] Exercise 3 A rotor with @ and o orientations performs a hindered rotation described by the Hamiltonian 0 h = AL + B

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9 Exercise 3 A Rotor With And O Orientations Performs A Hindered Rotation Described By The Hamiltonian 0 H Al B 1 (34 KiB) Viewed 14 times

[9] Exercise 3 A rotor with @ and o orientations performs a hindered rotation described by the Hamiltonian 0 h = AL + B cose with A >> B. In second order non-degenerate perturbation theory, compute the SP and D energy levels of this system and determine the corresponding energy eigenfunctions. Hint: You may use, without proof, the following result: cos0|1, m) (1 + m - 1) (1 + m - 1) 11+ m, m) + (21+1) (21+1) (1 + 1) (1 - m) 12 - m, m) (21 + 1) (21 - 1) (10)