Part A The Bond Angle About Oxygen In Alcohols And Others Is Typically Quite Close To Tetrahedral 109 5 But Opens Up 1 (29.87 KiB) Viewed 14 times
Part A The Bond Angle About Oxygen In Alcohols And Others Is Typically Quite Close To Tetrahedral 109 5 But Opens Up 2 (23.25 KiB) Viewed 14 times
Part A The Bond Angle About Oxygen In Alcohols And Others Is Typically Quite Close To Tetrahedral 109 5 But Opens Up 3 (23.25 KiB) Viewed 14 times
Part A The bond angle about oxygen in alcohols and others is typically quite close to tetrahedral (109.5") but opens up significantly in response to extreme serc crowding such as in comparing fert butylcohol to di-tert-butyl ether Build tert-butyl alcohol and di-fort-butyl ether and optimize the structure of each using the HF/6- 31G' model Are the calculated bond angles involving oxygen in accord with the values given earlier, in particular with regard to the observed increase in bond anglo? Do you see any lengthening of the CO bond in the ether over that in the alcohol? If not, or if the effect is very small (<0.01 A) speculate why not Match the words in the left column to the appropriate blanks in the sentences on the right. Me, сме, Me, 109 130 This is entirely consistent with the notion that Although one pairs occupy space, they can be squeezed to relieve crowding. Another way to ruleve unfavorable steric interactions (without changing the position of the lone pairs) is to increase the CO bond distance very different C-O bond length for tert-butyl alcohol and di-tert-butyl A respectively, easier A and 1.425 are but the central bond angle has ope than bond stretching energetically much nearly identical
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