1. The figure below is an Arrhenius plot for the rearrangement of the 2,4,6,-tri-t-butylphenyl radical (H) and of its pe
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1. The figure below is an Arrhenius plot for the rearrangement of the 2,4,6,-tri-t-butylphenyl radical (H) and of its pe
1. The figure below is an Arrhenius plot for the rearrangement of the 2,4,6,-tri-t-butylphenyl radical (H) and of its perdeuterated analogue (D). (a) Estimate the kinetic isotope effect (k/k) at 125 K. (b) Estimate k/k using k, = 500 Nm-1 for the force constant of a C-H bond. =
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