2. A pure gaseous reactant A is prepared under refrigeration and is then fed into a thin-walled glass capillary tube ser
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2. A pure gaseous reactant A is prepared under refrigeration and is then fed into a thin-walled glass capillary tube ser
2. A pure gaseous reactant A is prepared under refrigeration and is then fed into a thin-walled glass capillary tube serving as a reaction vessel as demonstrated in Fig. 1. Bath of boiling water 1000 mm Hg Reaction vessel Fig. 1. The reaction vessel is rapidly immersed in a boiling water bath, where reactant A decomposes. Depending on the reaction, the following data are obtained: 30 61 60 68 90 72 120 75 180 78.5 240 81 cilo 360 84 600 87 94 Time, sec Length of capillary occupied by the reaction mixture, mm The stoichiometry of the decomposition is A R + S. Find a rate equation in units of moles, litres, and minutes which will satisfactorily represent this decomposition (write down your assumptions, extract the equation needed and solve graphically).
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