P11F.6 The highest kinetic energy electrons in the photoelectron spectrum of H₂O using 21.22 eV radiation are at about 9
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P11F.6 The highest kinetic energy electrons in the photoelectron spectrum of H₂O using 21.22 eV radiation are at about 9
P11F.6 The highest kinetic energy electrons in the photoelectron spectrum of H₂O using 21.22 eV radiation are at about 9 eV and show a large vibrational spacing of 0.41 eV. The symmetric stretching mode of the neutral H₂O molecule lies at 3652 cm¹. (a) What conclusions can be drawn from the nature of the orbital from which the electron is ejected? (b) In the same spectrum of H₂O, the band near 7.0 eV shows a long vibrational series with spacing 0.125 eV. The bending mode of H₂O lies at 1596 cm¯¹. What conclusions can you draw about the characteristics of the orbital occupied by the photoelectron?
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