- Consider A Hypothetical Molecule With A 311 Ground State And No Other Accessible Electronic States What Is Qe At The Li 1 (55.9 KiB) Viewed 18 times
- Consider A Hypothetical Molecule With A 311 Ground State And No Other Accessible Electronic States What Is Qe At The Li 2 (63.16 KiB) Viewed 18 times
- Consider A Hypothetical Molecule With A 311 Ground State And No Other Accessible Electronic States What Is Qe At The Li 3 (193.06 KiB) Viewed 18 times
Consider a hypothetical molecule with a 311 ground state and no other accessible electronic states. What is qe at the limits of low temperature and high temperature? 3113 3112 311 Low T 2 3 تير ه ن م له N m m nm High T 3 2 6 6 3 D. 2 3 12
The Electronic Contribution E = Assuming there is only one energetically accessible electronic state, q E = gĘ, the degeneracy. Most molecules have closed shell singlet ground states and q E = ge = 1. Exceptions include O23E-9 qe = ge = 3 NO2 2A1 q5 = ge = 2 E = a E = = g E = =
4 NO 211 is 2 x 2 fold degenerate but it has a spin-orbit splitting of 121 cm-1 so we must treat it as a two level system with each level two-fold degenerate, qE = ge = 2 +2e-BE a Partition function, qe = = 2 10 0 5 Temperature, kT/ɛ