Which among the following equation satisfies heterogeneous nucleation?

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answerhappygod
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Which among the following equation satisfies heterogeneous nucleation?

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a) ΔGhet = – V*(ΔGv – ΔGs) + Aγ – ΔGd
b) ΔGhet = – V*(ΔGv – ΔGs) – ΔGd
c) ΔGhet = – V*(ΔGv – ΔGs) + Aγ + ΔGd
d) ΔGhet = – V*(ΔGv – ΔGs) + Aγ
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