You will write two mechanisms. One from set a/b and one from set c/d.( for the first to pictures)
Mechanism A/B Propose detailed mechanisms to account for ONE of the following TWO transformations (use curved arrow notation to indicate electron flow). Clearly indicate the problem that you do not wished graded (X) CH Klosterman a) n SSI ©2022 KIUste H₂SO4 H₂0 2022 CHEM40C SSI H₂02022 man 2 J. Klosterman CHEM40C SS Ⓒ2022 J. Klosterman C SSI CHEM40C SSI erman 022 J. Klosterman 40C SSI b) 2022 J. Kian M40C SSI terman CHEM40C SSI CHEM40C SSI sterme H Ⓒ2022 J. Klos ©2022 J. Klosterman Ⓒ2022 J. KI CHEM40C SSI 2022 J. Klosterman CHEM40C SSI-Ⓒ2022 J. Klosterman CHEM40C SSI Ⓒ2022 J. CHEM40C S 22 Jorman H₂SO4 H₂O CHEMA erman O Klosterm HO CHEM40S! terman CHEM400 Kloste
Mechanism C/D Propose detailed mechanisms to account for ONE of the following TWO transformations (use curved arrow notation to indicate electron flow). Clearly indicate the problem that you do not wished graded (X) c) Skic Ⓒ202Kloster Na Klostean a CH SSI man CHEM40C SSI H2022 J. Kloster CSSI 2 J. Klosterman CHEM40C SSI Ⓒ2022 J. Klosterman CHEM40C SSI Ⓒ2022 J. Klosterman CHEM40C SSI ©2022 J. KI 2022 J. Klosterman CHEM40C SSI/ CHEM40C SSI man 2022 CHAMA orman erman 022 J. Klosterman 40C SSI man d) 2022 J. M40C SSIH terman НО. HCI CHEM40C SSI erman SSI CHEM EtOH CHEM40C SSI Ⓒ2022 J. Klosterman 2022 J/ 02 J. Klos CHEM40C S Klosterm To SSI terman CHEM400 Kloste
Draw the chemical structure of: a) three different carboxylic acid derivatives with five carbons in the molecular formula. Rank their reactivity from 1-3 where 3 reacts slowest with nucleophiles. Explain your i SI an CHEM40 CHEM40p J. Klosterman CHEM4soning in 1-2 sentences. SSI ©2022 J. Klosterman C Ⓒ2022 J. Kloste CHEM40C SSI ©2022 J. Klosterman HEM40C SSI -CHEM40C SSI b) the hemiacetal formed by the reaction of cyclohexanone with methanol in basic solution and the acetal formed in acidic solution. Explain in 1 doesn't form in basic solution. 22 form in b (or draw a picture to explain) why the acetal Ⓒ2022 J. Kentence DC SSI CHEM40C SSI 2012 picture terman ©202 the aceta CHEM40C SSI CHEM40C SSI ©2022 J. Klosterman 2022 J.K' Klosternfan c) hexanoic acid, propyl propionate and 1-ethoxy-3-methylbutane. Rank them according to boiling point (where 1 = highest bp). Explain y 222 1. Klosterman ostermath ©2022 J. Klostermarour reasoning in m OSSI Ⓒ2022 J. Kloster tentences (Rank the Picture to be EM40C SSI Ⓒ2022 M40C SSI Ⓒ2022 J. EM40C S
. CHEM40C S CHEM40C SS EM40C SSI losterman losterman d) two different molecules with the formula CsH&O that contain carbonyl functional groups; make one that can act as an electrophile in a Michael addition and one that can act as a nucleophile in a Robinson-Annulation reaction. Label the carbons which act as nucleophiles/electrophiles in the Robinson-Annulation with 8- or 8+, J. Klostern with Ⓒ2022 J. Klösterectively. M40C SSI Ⓒ2022 J. Kloster ©20 CHEM4 CHEM40C S 2022 J. Klosterm 2022 Klosterman ©2022 J. Klostermante CHEM40C SSI CHEM40C SSI
You will write two mechanisms. One from set a/b and one from set c/d.( for the first to pictures)
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