2. How many signals (peaks) would you see in the fully decoupled 13C NMR spectrum for each of following molecules? (.e.
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2. How many signals (peaks) would you see in the fully decoupled 13C NMR spectrum for each of following molecules? (.e.
#5. Describe the differences that one would observe in the 1H NMR spectrum bewteen the following two molecules.
#6. Which compound fits the 1H-NMR spectrum below? Assign the signals to the hydrogens in the molecule giving rise to the signal.
2. How many signals (peaks) would you see in the fully decoupled 13C NMR spectrum for each of following molecules? (.e. no splitting is observed, all carbons appear as a singlet) pealh 6717 peains "" CH₂ CH₂ "CH Br of
4. The 1 NMR spectrum of an alcohol (and amine) often depends on several variables such concentration and temperature, Sketch the expected IH NMR spectrum of the following alcohol under each condition. Under conditions in (a) hydrogens on carbon do NOT split (couple) with hydrogens on oxygen. Under conditions in (b) hydrogens on carbon split (couple) with hydrogens on oxygen. For (c) explain the change in the spectrum. (0) (c) OH CH explain (c): conditions: high concentration or low temperature conditions: low concentration or high temperatura conditions:A drop of D₂O has been added to either (s) or (b)
S. Describe the differences that one would observe in the 1H NMR spectrums between the following two raclecules. GH₂
6. Which compound fits the IH-NMR spectrum below? Assign the signals to the hydrogen in the molecule giving rise to the signal. C₂H₂C1O PPM