Relative Intensity 100 80 6 · 20 . ասխապատրաստ 0 25 50 75 100 m/z 125 150 175 Mass Spectrometry Analysis Using the Mass
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Relative Intensity 100 80 6 · 20 . ասխապատրաստ 0 25 50 75 100 m/z 125 150 175 Mass Spectrometry Analysis Using the Mass
Mass Spectrometry Analysis Using the Mass Spectrometry Fragment Tables, answer the following questions to interpret the mass spectrometry spectrum for unknown 17. Note: The mass spectrum was collected with the mass spectrometer in positive mode. Hint: you may like to revisit this section once you have a better idea of the structure from interpreting the other spectra. Unknown 17 MS Spectrum What is the base peak? (Give your answer as a whole number, no decimal places). 91 What is the parent peak? (Give your answer as a whole number, no decimal places). 172 What is the likely structure of the fragment ion at 91 m/z? ◆ What is the likely structure of the radical lost to give the fragment ion at 91 m/z? ◆ H. multiple H. CH3. NH2. OH. H20 CH2=CH2 CO• CH3CH2. CHO. •OCH3 •CH2OH CI. [CH3C=0]. CH3CH2CH2- [COOH]• •OCH2CH3 •C6H5 •Br [C7H7]. [CH3]+ [CH3CH2]+ [CHO]+ [CH2OH]+ [OCH3]+ [C3H6].+ [O=CCH3]+ [CH3CH2CH2]+ [O=C=NH2]+ [COOH]+ [C(CH3)3]+ [C2H5CO]+ [C4H9]+ [C5H5]+ [C4H6O]•+ [C3H7CO]+ [C4H90]++ [C6H4]++ [C6H5]+ [C7H7] + m/z m/z