According to data from NIST, OH radical molecule
constant
Te - minimum electronic energy (cm-1)
ωe - vibrational constant – first term (cm-1)
re - internuclear distance (Å)
Trans. - observed transition(s) corresponding to electronic
state
Molecular orbital of OH radical is similar (a)
2.1 Based on the data from NIST, plot the bottom state and
excited electronic placement in Figures (b), (c), and (d) above,
and explain the reason below.
(b)
(c)
(d)
State Te(cm) We(cm) Wexe(cm) re(Å) Trans. C 2E+ 89459.1 1232.9 19.1 2.0461 C → A B 2E+ 69774 [660.0] [1.8698] BA A 25+ 32684.1 3178.86 92.917 1.0121 A X X? 0 3737.761 84.8813 0.96966
(а) 2ро* (b) 2ро* (c) 2ра* (d) 2ро* 1s 2рт 2px 2px - 2ру. 2рл 2рл 2ри 2рт 2ро | 2ро 2ро 2ро 2ѕо 2ѕо 2ѕо 2s 2ѕо 1s 1s 1s 1s 1s o ОН H Х2П А22* в22*
(0 = „“)II, X → (I = ,")+37 V
ỉ II (v" =1) — Ã ?g+(v' = 1)
According to data from NIST, OH radical molecule constant Te - minimum electronic energy (cm-1) ωe - vibrational constan
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