H:O Editing CI _12+ Cl-Fe- Cis isomer of Fe(9-crown-3)Cl₂ H H: C 0¹ C: C Each corner is a H H carbon atom HH Lewis Dot S

[answerhappygod]

H O Editing Ci 12 Cl Fe Cis Isomer Of Fe 9 Crown 3 Cl H H C 0 C C Each Corner Is A H H Carbon Atom Hh Lewis Dot S 1 (55.12 KiB) Viewed 63 times

H:O Editing CI _12+ Cl-Fe- Cis isomer of Fe(9-crown-3)Cl₂ H H: C 0¹ C: C Each corner is a H H carbon atom HH Lewis Dot Structure a. The cis isomer is drawn above, draw the trans isomer of Fe(9-crown-3)Cl₂. b. What is the most likely geometry for the trans isomer of Fe(9-crown-3)Cl₂? c. In the drawing of the trans isomer label the positions of each ligand as either axial or equatorial. d. Does either Fe(9-crown-3)Cl, geometric isomer (cis or trans) have an optical isomer? Explain your answer by 'either drawing the optical isomer or write a step by step methods report explaining how to determine if an optical isomer exists. e. Derive the crystal field splitting diagram for the trans isomer based on the geometry identified in part b. You should clearly show the relative energies of the d orbitals and justify the differences in energy. To clearly communicate your answer, show the xyz plane relative to your 3D drawing of the trans isomer (so we are both thinking in the same planes). f. An experiment shows the Fe*2 ion in the complex ion is low spin. Do you expect the complex ion of the trans isomer to be diamagnetic or paramagnetic? Support your answer by showing the electron distribution in the crystal field splitting diagram drawn in part e.