Experimental pressure-temperature Phase Diagrams of 4 pure compounds (unary systems) (1: CCI,)) (2: CCI, Br) (3: CCI,Br)

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Experimental Pressure Temperature Phase Diagrams Of 4 Pure Compounds Unary Systems 1 Cci 2 Cci Br 3 Cci Br 1 (81.67 KiB) Viewed 11 times

Experimental pressure-temperature Phase Diagrams of 4 pure compounds (unary systems) (1: CCI,)) (2: CCI, Br) (3: CCI,Br) (4: CBra) 2802 360 p/MPa 15 30 L FCC 430 360 1 270-000 IL 1 LI 1 1 320 320 26044 360 L 1 1 1 1 320 iba OIA 61 IN 280 1 IR 1 390 1 1 T/K LM R 1 1 FOC 280 1 I 280 M IM 350 01 M 240 60000mmande M 1 (a) 1 1 1 foronto FCC 1 (d) (b) 240 1 FCC! (C) 240 310 0 1100 200 300 0 P/MPa 0 1 100 200 300 P/MPa 9 100 200 300 p/MPa 100 200 300 P/MPa Excersise: Draw schematically the Gibbs functions of the involved phases (M, R, FCC and L) at the selected pressures (dashed red lines) as a function of temperature. Note: For substance (1), the circles correspond to the melting of the metastable FCC phase.