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23. You are given a Voltaic cell (all concentrations are 1.0M) that is operating at 25.0°C. The cell that holds the 1.0 M PESO. has a Puis electrode, the cell that contains 1.0M Na 50, 1.0M NaOH. 1.0 M Na,3,0, has a graphite electrode. A salt bridge connects the two cells, and a digital voltmeter is placed between the electrodes (see below). Assuming this Voltaic 1.0M Na, so 1.0M NaOHL L.OM Na, Here are the pertinent reduction potentials E (V) - 1.13 Reduction half-reaction 250}-(aq) + 2H,O(1) + 2e - 5.03- +40H-(am) Pe?(aq) + 20" - Pt(s) +1.20

Write out the cell in cell notation h The molarity of platinum sulfate is changed to 2.0 M, all other ions are kept at 1.0 M. The temperature in the lab is now 29.0°C. What is the new voltage E 1. What is AG now?

чби - toa) . +3 Am 280, 3-lay $.0.2-+ 880, lay) taitoli +20 Exod -1.13 v Pt (s) Pest ge- pt Eseda +1:20 W H 350,- +2H0+de- $0.2- + UDH- Ex: +1:13V f4 2502 +20 ypt & Sou 4 Чон- Ecotrade - Esnode Caut 1.13 e Call Eau 0.07 V ACE - nf Econ AGE - 2 X 46500X0.07 Aliceu - 13510 cv So, 0, 1 IL PEE/Ptes) tal Ptzt Saft Cathode Bridge anod