7.5. The reaction of trans-PdAr L2 (A, Ar=m-tolyl, L = PEt,Ph) with Mel gives 75% of m-xylene and 25% of 3,3-bitolyl. Ex
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7.5. The reaction of trans-PdAr L2 (A, Ar=m-tolyl, L = PEt,Ph) with Mel gives 75% of m-xylene and 25% of 3,3-bitolyl. Ex
7.5. The reaction of trans-PdAr L2 (A, Ar=m-tolyl, L = PEt,Ph) with Mel gives 75% of m-xylene and 25% of 3,3-bitolyl. Explain how these products might be formed and list the possible Pd-containing products of the reactions. When the reaction of A was carried out with CDI in the presence of do-PdMeIL (B), both do- and dy xylene were formed. A also reacts with B give m-xylene and 3,3-bitolyl. How does this second result modify your view of the mechanism? WISHO all
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