CHALLENGE PROBLEMS: (Do at least 3) 1. Assuming that N= 25, show the derivation of the third order (1 order in S, 2nd or

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Challenge Problems Do At Least 3 1 Assuming That N 25 Show The Derivation Of The Third Order 1 Order In S 2nd Or 1 (63.91 KiB) Viewed 20 times

CHALLENGE PROBLEMS: (Do at least 3) 1. Assuming that N= 25, show the derivation of the third order (1 order in S, 2nd order in Nu) integrated rate laws by the integration of the instantaneous rate laws. 3rd order 8kt + 1 S. 2 (S. -x) 2. Assuming that N, 25, show that the integrated rate law for the third order initial rate law is In No - 2x So-x + In S. N. 3)-(N, -25. 23,18 v tal-(N , -25.)' * N) 1 No - 2x No k1 3. Show that differentiation of the equation in challenge question (2) gives the third order rate law. 4. Occasionally, in kinetic investigations it is noticed that in the plotting of the Arrhenius or Eyring equations that the slope of the line changes above or below a particular temperature. When this occurs the line may continue to be linear with a different slope or it may show curvature indicating that the plot is not linear in the new temperature range. Explain what the change in the behavior of the plot represents. 5. Show that, for (N, *25.), the derivation of the second and third order integrated rate laws based on the change in the concentration of the haloaromatic provides the same results as