2- CgHg²- is a cyclic organic ion with the structure showm here on the left. Considering only the T bonds and not the o bonds, cyclooctatriene dianion can be discribed by the diagam on the right. Complete the MO diagram by assigning the appropriate numbers of p electrons. (1) H H H (2) -(3) - (5) 2 | F "5 13
(A) There are 8 atomic orbitals for the pi bonds, therefore there are 8 molecular orbitals for CgHg2- (B) The hybridization of the 8 carbons is (C) Based on the MO diagram, what is the magnetic state of the dianion?, (D) The LUMO is (E) The HOMO is (F) In this MO, there are ◆ bonding orbitals, (G) In this MO, there are antibonding orbitals, (H) In this MO, there are nonbonding orbitals, <> <> <>
True False sp sp2 sp3 diamagnetic paramagnetic TT1 π2 and +3 π4 and 5 π6 and π7 π8 1
2- CgHg²- is a cyclic organic ion with the structure showm here on the left. Considering only the T bonds and not the o
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2- CgHg²- is a cyclic organic ion with the structure showm here on the left. Considering only the T bonds and not the o
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