- The Entropy Increase Produced By Mixing Two Liquids Is Based On The Formula For The Entropy Change That Results From The 1 (61.99 KiB) Viewed 12 times
The entropy increase produced by mixing two liquids is based on the formula for the entropy change that results from the
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The entropy increase produced by mixing two liquids is based on the formula for the entropy change that results from the
The entropy increase produced by mixing two liquids is based on the formula for the entropy change that results from the isothermal expansion of a fluid from volume Vential to volume V ASnRin(). Suppose two liquids are mixed together to make a binary solution. One liquid has initial volume V₁ and the second liquid has initial volume V₂. Assume there is no change in the volumes of the individual liquids and if the liquids mix randomly the final volume is exactly Vjoi = V₁ + V₂. Then the total entropy change for mixing the two liquids is: $₁ = ASme=AS₁ + AS, = -R(nin+₂) = R(n. Ind+nInd) where and are x = the volume tractions of liquids 1 and 2, respectively. Note like mole fractions volume fractions must sum to one: +1. ▾ Part B Suppose 1:00 moi of liquid 1 is mixed with 2.00 molas of liquid 2. Assume V₁ == 1.80 x 10 mmol ¹ Calculate the volume fraction of liquid 1. -ΘΕ ΑΣΦ + A C P ? -0.667 Submit Previous Answers Request Answer ▾ Part C * Incorrect; Try Again; 4 attempts remaining Using your results from Part B, calculate the entropy of mixing. ▾ ASmix ✓ Submit Part D X1- Submit Part E For the liquids described in Part B, calculate the mole fraction for liquid 1, i.e. Xi. p= DA + • C MAI ? Value Submit Part F Request Answer IVE ΑΣΦ ← A C 1503 ? The parameter x = measures the relative size of the two types of molecules. If molecules 1 and 2 are roughly the same size, z 1. But il molecule 2 is much larger than molecule 1, 2 > 1. Assume that 1 mole of liquid 1 is mixed with 2 moles of lquid 2. but assume also a 10. Calculate the volume fraction ΙΠ ΑΣΦ Request Answer ASmiz = Units Request Answer CH 1 → O Using your results from part E, calculate the entropy of mixing. Value Submit Request Answer ? A A C Units ?