Example 2. In vibrational spectra of HCl molecule, an intense fundamental at 2886 cm- and a weak first overtone at 5668
Posted: Thu Mar 17, 2022 11:31 am
Example 2. In vibrational spectra of HCl molecule, an intense fundamental at 2886 cm- and a weak first overtone at 5668 cm- are observed. Find the equilibrium frequency, un harmonic constant and force constant of the molecule. Solution: we(1 – 2x.) v' = 1 Vobs = 20.(1 – 3x) v' = 2 Vobs