Questions 1 and 2 refer to the four MO's of butadiene shown below. Dark shading indicates a positive sign. 0000 0000 og
Posted: Sun Feb 13, 2022 8:04 am
Questions 1 and 2 refer to the four MO's of butadiene shown below. Dark shading indicates a positive sign. 0000 0000 og ogo ОО B D (I point) 1. Normally in the ground state) there are no electrons in C and 2. In the ground state, is the HOMO. (1 point) 3. Choose any four reactions. Fill in the boxes to correctly complete cach reaction. Only the first four will be graded if you answer all five. (4 points) (14.9a, 14.10b similar. 14.26b) . HAC C(CH3)2 C(CH3)-MgBr Н20 HE B OH MCPBA Н20 NaOH TOH ONa HBr D Br not HBO organic E Br KOH Н.0 HCI OH There are more questions on the back.
4. Draw only the propagation steps that explain the reaction shown below. Don't draw anything in the box. (2 points) Br NBS, Br2 2. CH,CH2CH2CH2C=CH2 H - HBO CH-CH-CH2CHC=CH H ,
5. Choose two of the reactions shown below. Draw the mechanism that explains each reaction. Don't draw anything in the boxes. You may use the back of this page if you need more space. (4 points) OH Philic CH2 + H2O Phine-CH2OH HClcat Et Et Prima OH CH2 + H2O NaOH cat Phic-CH2OH Et Et Br Hinc Hilton + KOH -CH2 I OH KBr CH2 Ph Ph
4. Draw only the propagation steps that explain the reaction shown below. Don't draw anything in the box. (2 points) Br NBS, Br2 2. CH,CH2CH2CH2C=CH2 H - HBO CH-CH-CH2CHC=CH H ,
5. Choose two of the reactions shown below. Draw the mechanism that explains each reaction. Don't draw anything in the boxes. You may use the back of this page if you need more space. (4 points) OH Philic CH2 + H2O Phine-CH2OH HClcat Et Et Prima OH CH2 + H2O NaOH cat Phic-CH2OH Et Et Br Hinc Hilton + KOH -CH2 I OH KBr CH2 Ph Ph