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In the Coulomb model of a hydrogen atom, the energy eigenfunctions take the form Unim(r,0,0)=Rnt (r) Yim (0,0). We consi

Posted: Thu Jun 09, 2022 3:39 pm
by answerhappygod
In The Coulomb Model Of A Hydrogen Atom The Energy Eigenfunctions Take The Form Unim R 0 0 Rnt R Yim 0 0 We Consi 1
In The Coulomb Model Of A Hydrogen Atom The Energy Eigenfunctions Take The Form Unim R 0 0 Rnt R Yim 0 0 We Consi 1 (117.16 KiB) Viewed 129 times
In the Coulomb model of a hydrogen atom, the energy eigenfunctions take the form Unim(r,0,0)=Rnt (r) Yim (0,0). We consider here a state with n = 2, 1 = 1 and m= +1 for which the normalized radial function and spherical harmonic are 1 ¹/2 1/2 3 R2,1 (r) = (2445) re-¹/200 and Y₁,1(0,0) sin eti 8T (a) If the atom makes a radiative transition from the state described by 2,1,1(r, 0, 0) to a state with n = 3, what is the energy of the absorbed photon? What are the possible I and m quantum numbers of the final state of the atom after the transition? (b) Write down an expression for the probability of finding an electron-proton separation in the small range between r and r + dr in the state described by 2,1,1(r, 0, 0). Hence find the most probable value of the electron-proton separation in this state. (e) Find the expectation value of the electron-proton separation in the state described by 2,1,1(r, 0, 0). (d) Suppose that a hydrogen atom in the unperturbed state 2,1,1(r, 0,6) is subject to a small perturbation SĤ= where C is a constant. Use perturbation theory to find the first-order correction to the energy of the state due to this perturbation. (e) Let C = ERa²a, where a = 1/137. Is the perturbation theory of part (d) valid? Suppose instead of hydrogen, we consider the hydrogenic ion Fe²5+. Use a scaling argument to determine if the first order perturbation theory method remains valid (assume that C does not scale with Z or A and ignore any reduced mass effects). You may find the following integral useful in parts (c) and (d): fre u"eu/e du = n!e"+1 for c> 0 and n = 1, 2, 3,....