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Compound 84 is a liquid (boiling point 81-82"C@ 14 mm Hg), that reacts with p-toluenesulfonyl chloride to form a sulfona
Posted: Thu Jun 09, 2022 8:25 am
by answerhappygod
- Compound 84 Is A Liquid Boiling Point 81 82 C 14 Mm Hg That Reacts With P Toluenesulfonyl Chloride To Form A Sulfona 1 (43.37 KiB) Viewed 76 times
- Compound 84 Is A Liquid Boiling Point 81 82 C 14 Mm Hg That Reacts With P Toluenesulfonyl Chloride To Form A Sulfona 2 (43.37 KiB) Viewed 76 times
Compound 84 is a liquid (boiling point 81-82"C@ 14 mm Hg), that reacts with p-toluenesulfonyl chloride to form a sulfonamide which is not soluble in strong base (this is the "Hindsburg test"). The Mass, IR, and H NMR spectra, along with C NMR data, are given below. Elemental Analysis: C, 78.46; H, 8.47; N, 13.07. Mass Spectrum 107 100 110 120 130 140 160 180 IN 101200 me Wave Number, cm-t 1300 1200 11 Wavelength, microns "C Spectral Data: singlet, 143.5 ppm doublet, 129.3 ppm. doublet, 116.9 ppm doublet, 112.3 ppm quartet, 40.3 ppm H NMR Absorbance Intensity Infrared Spectrum 4000 3000 2500 2000 80 70 1500 Structure: C3000 Brooks Cole Publishing Com