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Using the knowledge you have gained regarding EOS and Calculate V (cm³/mol) and Z for: Vapor Methanol at 300°C and 20 bar: a) ideal gas equation b) The virial coefficient B = -600 cm³/mol c) The Van der Waals Eqn. of State a(T,) 0 E S2 4 Ze 0 0 1/8 27/64 3/8 vdW (1873) RK (1949) SRK (1972) 1 7,-1/2 1 0 0.08664 0.42748 1/3 aSRK (T; 0) 1 0 0.08664 0.42748 1/3 PR (1976) APR(T,: a): 1+ √2 1-√2 0.07780 0.45724 0.30740 TasRK(Tr; a)= [1 + (0.480 +1.574 -0.1762)(1-7,212 apR(T )= [1 + (0.37464 +1.54226 -0.269922) (1-7,2)1² PV B Z= =1+ RT V PV B C Z= =1+ RT V + √²
P= RT a(7) V-b (V+eb)(V+ ab) Acetone Methyl ethyl ketone Diethyl ether Methyl 1-butyl ether Methanol Ethanol 1-Propanol 1-Butanol 1-Hexanol 2-Propanol Phenol Molar mass Ve cm¹-mol-¹ T/K @) TJK PJbar Ze 0.307 508.2 47.01 0.233 209. 329.4 58.080 72.107 0.323 535.5 41.50 0.249 267. 352.8 0.281 466.7 36.40 0.263 280. 307.6 74.123 88.150 0.266 497.1 34.30 0.273 329. 328.4 118. 337.9 61.48 0.240 167. 351.4 32.042 0.564 512.6 80.97 0.224 46.069 0.645 513.9 60.096 0.622 536.8 74.123 0.594 563.1 51.75 0.254 219. 370.4 44.23 0.260 275. 390.8 102.177 0.579 611.4 35.10 0.263 381. 430.6 60.096 0.668 508.3 47.62 0.248 220. 355.4 94.113 0.444 694.3 61.30 0.243 229. 455.0 Values of the Universal Gas Constant R
Values of the Universal Gas Constant R Units Values of R Units J-K-1.mor1 83.14472 L-mbar-K1-mol L-atm-K-1.mol-¹ 8.314472 105 m³-bar-K1.mol1¹ m³.atm-K¹.mor¹ 10.73159 ft³-psi-R¹-Ib-mol¹ L-kPa-K¹-mol1 0.73024 ft³.atm.R¹-Ib-mol¹ m³. Pa-K¹.mol-¹ 1.98588 Btu-R1-Ib-mol1 cm³.atm-K¹-mol¹ 62.36367 L-torr-K¹-mol1 Values of R 8.314472 0.082057 8.205745x105 8.314472 8.314472 82.05745