The absorbance spectrum of the [TI(H20).]3+ complex-ion is shown below. Tiº = [Ar]3d24s2 and H2O is a low crystal field
Posted: Tue May 17, 2022 9:45 am
The absorbance spectrum of the [TI(H20).]3+ complex-ion is shown below. Tiº = [Ar]3d24s2 and H2O is a low crystal field splitting energy ligand. R O YO Wavelength (mm) 667 500 400 333 1000 LO 0.5 loge - 0.0 -0.5 10,000 15,000 20,000 25.000 30,000 Frequency (em) Electronic spectrum of 10.1 M aqueous solution of (TKH,021-
(a) According to the selection rules, how many electronic transitions are expected for this complex? (2 marks) (b) Why is there a shoulder on the low wavenumber side of the large band in this spectrum? (4 marks) (c) What colour would this solution have? Briefly explain your answer (4 marks)
(a) According to the selection rules, how many electronic transitions are expected for this complex? (2 marks) (b) Why is there a shoulder on the low wavenumber side of the large band in this spectrum? (4 marks) (c) What colour would this solution have? Briefly explain your answer (4 marks)