For hydrogen at pt (a) Assign the voltametric features between +0.5 and 1.0 V and between-1.5 and -2.0 V to appropriate
Posted: Mon May 16, 2022 11:16 pm
For hydrogen at pt (a) Assign the voltametric features between +0.5 and 1.0 V and between-1.5 and -2.0 V to appropriate electrode reactions. Comment on the heterogeneous and homogeneous kinetics pertaining to these electrode reactions. (b) Why does the falloff in current appear between 0.7 and 1.0 V vs. QRE? (c) What constitutes the anodic and cathodic currents seen at -1.0 V vs. QRE? Scan rate (mV/sec) First Wave Second Wave ipc іра -Epc -Epa ipc -Epe -Ep/2 (uA) (MA) (V vs. SCE) (uA) (V vs. SCE) 430 298 203 91 73 8.0 6.7 5.2 3.4 3.0 8.0 6.7 5.2 3.4 2.9 1.42 1.42 1.42 1.42 1.42 1.36 1.36 1.36 1.36 1.36 7.0 6.5 4.7 3.0 2.8 2.10 2.09 2.08 2.07 2.06 2.00 2.00 2.00 1.99 1.98