7) (10 points) Estimate the anharmonicity constant Xe for 'H''Br from the data in table 12.2 (9th edition). By what fact
Posted: Mon May 16, 2022 11:10 pm
7) (10 points) Estimate the anharmonicity constant Xe for 'H''Br from the data in table 12.2 (9th edition). By what factor does the anharmonicity change when H is replaced by T?
Table 12.2 Properties of diatomic molecules Vicm B/K B/cm @,/K Rip ky/Nm" Dil mal 3341 42.9 2 TH 6332 87.6 100 74.138 "H THE H'a Br 2321.8 4400.39 3118.46 4138.32 2990.95 2648.98 2308.09 2358.07 1580.36 29.8 60.864 30.442 20.956 10.593 2 255.8 132.1 439.6 564.4 427.7 4487 5955 4304 3812 3321 3393 2274 43.8 30.2 15.2 12.2 9.37 2.88 2.08 1.27 362.7 2949 WN 100 5749 577.0 965.7 516 411.5 313.8 2295.8 1176,8 445.1 3223 1903.17 245.9 1 2 8.465 6.511 1.9987 1.4457 0.8828 0.2441 1.9313 0.0809 WO 74.154 91.680 127.45 141.44 160.92 109.76 120.75 141.78 198.25 112.81 283,3 2 F 2 891.8 559.71 2170.21 323.2 1283 805 3122 941.7 493.5 1544 2393 1071.8 190.2 2 CITO Br"Br 0.351 2.78 10.116 465 Data AIP
Table 12.2 Properties of diatomic molecules Vicm B/K B/cm @,/K Rip ky/Nm" Dil mal 3341 42.9 2 TH 6332 87.6 100 74.138 "H THE H'a Br 2321.8 4400.39 3118.46 4138.32 2990.95 2648.98 2308.09 2358.07 1580.36 29.8 60.864 30.442 20.956 10.593 2 255.8 132.1 439.6 564.4 427.7 4487 5955 4304 3812 3321 3393 2274 43.8 30.2 15.2 12.2 9.37 2.88 2.08 1.27 362.7 2949 WN 100 5749 577.0 965.7 516 411.5 313.8 2295.8 1176,8 445.1 3223 1903.17 245.9 1 2 8.465 6.511 1.9987 1.4457 0.8828 0.2441 1.9313 0.0809 WO 74.154 91.680 127.45 141.44 160.92 109.76 120.75 141.78 198.25 112.81 283,3 2 F 2 891.8 559.71 2170.21 323.2 1283 805 3122 941.7 493.5 1544 2393 1071.8 190.2 2 CITO Br"Br 0.351 2.78 10.116 465 Data AIP