Answer Happy

11) (20 points) Given the following spectra for HCl and DCI, calculate the value of Band the bond distance of HCI. P Branch Q Branch Branch 2 1 2 3 4 5 6 7 8 9 10 11 12 m Values 0 1 2 3 4 5 6 7 89 10 11 r Values 11 10 6 5 4 3 2 1 1 1 Absorbance Whenumber om Figure 3. The vibrational rotational infrared spectrum of HC R Branch P Branch Branch 0.01 98 7 6 5 4 3 21 0 1 2 3 4 5 6 7 8 9 1" values 1 2 3 4 5 6 7 8 9 10 m values 0.008 -9 -8-7-6 -54 -3 -2 -1 0.006 Absorbance 0.004 0.002 2177 2227 1977 2027 2017 2127 Wavnumber(cm) Figure 7. Spectrum of DCI with J and m values and labeled and R branch. Vibrational rotational infrared spectrum for diatomic DCI.

) (20 points) Given the following spectra for HCl and DCI, calculate the value of Band the bond distance of HCI. Branch Branch Branch -11-30-9-8-7-6-5-4-3-2-1 11 10 9 8 2 65 1 2 3 4 5 6 7 8 9 10 11 12 Values 0 1 2 3 4 5 6 7 8 9 10 11 1 1 Dance 2010 Figure 3 The vibrational rotational infrared spectrum of HCI R Branch P Branch Q Branch 001 9 8 7 5 4 3 2 1 0 1 2 3 4 5 6 7 8 9 values 1 2 3 4 5 6 7 8 9 10 values 0.000 -9 -5 4 3 2 1 0.00 Absorbance heltuin 2017 Weber Figure 7. Spectrum of DCI with J and m values and labeled P and R branch. Vibrational rotational infrared spectrum for dintomic DCI.