Q1(A) (5) A binary liquid mixture is in equilibrium with its vapor at 300K. The liquid mole fraction of species 1 is 0.4
Posted: Mon May 16, 2022 12:51 pm
Q1(A) (5) A binary liquid mixture is in equilibrium with its vapor at 300K. The liquid mole fraction of species 1 is 0.4 and the molar excess Gibbs free energy is 2001/mol If 7, -1.09, calculate the value of 7, denotes liquid-phase activity coefficient of species i in the binary mixture. Starting with the simplest form of virial equation prove that the fugacity of a pure liquid species at a pressure (P) and temperature (T) is given by the following expression [B peut + v'(P-psuty] f - prat exp 21(8) RT where B, psat and v' are second virial coefficient, saturation vapour pressure and molar volume of the pure liquid, respectively. List your assumptions (5)