Consider the electrochemical cell Pt(s) | Cut, Cu2+ (1 M) || H* (1 M), H₂ (g. 1 atm) | Pt(s). Which of the following is
Posted: Fri May 06, 2022 7:52 am
Consider the electrochemical cell Pt(s) | Cut, Cu2+ (1 M) || H* (1 M), H₂ (g. 1 atm) | Pt(s). Which of the following is correct about AG, K and spontaneity of the redox reaction as it is written for this cell at 25 °C: a) AG = 29.0 kJ, k is about 8 x 10-6, and it is NOT spontaneous. b) AG-29.0 kJ, K = 1 × 10-5, and it is spontaneous. O AG-14.5 kJ, K = 340, and it is NOT spontaneous. c) d) AG = 29.0 kJ, K = 9 × 10-27, and it is spontaneous.. e) AG 14.5 kJ, K = 0.0029, and it is spontaneous.
Ionization Constants of Acids and Bases at 25°C (K=1.0x10¹) Name of Acid Formula K K Acetic acid Arsenic acid CHICOOH K₁ 1.8x10 H₂ASO Acetylsalicylic Acid 5.6x10 1.0x10 нс.н.о. 3.0x10¹ Arsenous acid 3.3x10+ H₂Asos Ascorbic acid 5.1x10 Н.с.н. C H.COOH 8.0x10 Benzoic acid 1.6x10¹ 6.5x10 Carbonic acid H₂CO) 4.2x10 4.8x10 Formic acid HCOOH 1.7x10 Hydrochloric acid HCI Strong HCN 4.9x10- Hydrocyanic acid Hydrofluoric acid Hydrosulfuric acid HF 7.1x104 H₂S 9.5x10 1x10-19 Hypochlorous acid HOCI 3.5x10 Nitrous acid HNO: 4.5x104 Oxalic acid H₂C₂O4 6.5x10 6.1x10 Phosphoric acid H₂PO4 7.5x10³ 6.2x10 Sulfuric acid H₂SO Very Large 1.3x102 Sulfurous acid H₂SO3 1.3x102 6.3x10 К. 1.8x10- 3.8x10-10 5.4x10-4 6.9x10 5.6x104 3.0x10-6 1.1x10-0 4.4x10 1.7x10-9 5.6x10- 6.4x10-5 1.5x10-14 Name of Base Ammonia Aniline Diethylamine Dimethylamine Ethylamine Hydrazine. Hydroxylamine Methylamine Pyridine Triethylamine Trimethylamine Formula NH₂ CHINH (C₂Hs)2NH (CH3)2NH C₂HsNH₂ H₂NNH₂ HẠNH, CHÍNH: CsHsN (C₂Hs)aN (CHIẾN H₂NCONH₂ 4.8x10-13 Solubility Product Constants at 25°C Formula Kap Agar 77x10 AgCl 10x10 Agico. 6.1x10¹ AgiCro 1.2x10 Agl 8.3x10 Ag50. Al(OH) BaCO. BaFi Ba50. Baa CaCO Caf Ca(OH) Caso. Cos CuBr Cul Cu(OH)2 Cus FGS Fe(OH): Fe(OH) Hg₂80 Mg(OH) PbBr₂ PbCrO Pola PbS 1.5x10 1.8x10 8.1x10 1.7x10 1.1x10 1.8x10 SnS SrCO₂ SrSO ZnS 8.7×10 40x10 80x10 2.4x10 4.0x10 4.2x10 5.1x104 2.2x10 6.0x10 6.0x10-19 1.6x1014 1.1x10 6,5x10 1,2x10 6.6x104 2.0x104 1.4x10 3.4x102 1.0x10 1.6x10 3.8x10 3.0x10-27
Ionization Constants of Acids and Bases at 25°C (K=1.0x10¹) Name of Acid Formula K K Acetic acid Arsenic acid CHICOOH K₁ 1.8x10 H₂ASO Acetylsalicylic Acid 5.6x10 1.0x10 нс.н.о. 3.0x10¹ Arsenous acid 3.3x10+ H₂Asos Ascorbic acid 5.1x10 Н.с.н. C H.COOH 8.0x10 Benzoic acid 1.6x10¹ 6.5x10 Carbonic acid H₂CO) 4.2x10 4.8x10 Formic acid HCOOH 1.7x10 Hydrochloric acid HCI Strong HCN 4.9x10- Hydrocyanic acid Hydrofluoric acid Hydrosulfuric acid HF 7.1x104 H₂S 9.5x10 1x10-19 Hypochlorous acid HOCI 3.5x10 Nitrous acid HNO: 4.5x104 Oxalic acid H₂C₂O4 6.5x10 6.1x10 Phosphoric acid H₂PO4 7.5x10³ 6.2x10 Sulfuric acid H₂SO Very Large 1.3x102 Sulfurous acid H₂SO3 1.3x102 6.3x10 К. 1.8x10- 3.8x10-10 5.4x10-4 6.9x10 5.6x104 3.0x10-6 1.1x10-0 4.4x10 1.7x10-9 5.6x10- 6.4x10-5 1.5x10-14 Name of Base Ammonia Aniline Diethylamine Dimethylamine Ethylamine Hydrazine. Hydroxylamine Methylamine Pyridine Triethylamine Trimethylamine Formula NH₂ CHINH (C₂Hs)2NH (CH3)2NH C₂HsNH₂ H₂NNH₂ HẠNH, CHÍNH: CsHsN (C₂Hs)aN (CHIẾN H₂NCONH₂ 4.8x10-13 Solubility Product Constants at 25°C Formula Kap Agar 77x10 AgCl 10x10 Agico. 6.1x10¹ AgiCro 1.2x10 Agl 8.3x10 Ag50. Al(OH) BaCO. BaFi Ba50. Baa CaCO Caf Ca(OH) Caso. Cos CuBr Cul Cu(OH)2 Cus FGS Fe(OH): Fe(OH) Hg₂80 Mg(OH) PbBr₂ PbCrO Pola PbS 1.5x10 1.8x10 8.1x10 1.7x10 1.1x10 1.8x10 SnS SrCO₂ SrSO ZnS 8.7×10 40x10 80x10 2.4x10 4.0x10 4.2x10 5.1x104 2.2x10 6.0x10 6.0x10-19 1.6x1014 1.1x10 6,5x10 1,2x10 6.6x104 2.0x104 1.4x10 3.4x102 1.0x10 1.6x10 3.8x10 3.0x10-27