5. Dinitrogen tetroxide is 18.46 per cent dissociated at 298 K and 1.00 bar in the equilibrium N2O4(g) 2NO2(g). Assuming
Posted: Wed May 04, 2022 3:18 pm
4 Sub-Questions.
[answers Policy: One question per post - questions with sub-parts are
fine, but posts with multiple questions will be closed]
(★Please give complete and correct answers if you choose this
question, otherwise please don't answer it and waste my quota.
Thank you)
5. Dinitrogen tetroxide is 18.46 per cent dissociated at 298 K and 1.00 bar in the equilibrium N2O4(g) 2NO2(g). Assuming that the gases are perfect. (a) calculate Kp and ArG* at 298 K. (4 points) d ln Kp (b) Evaluate (the other form of the van't Hoff equation). (2 points) d (1/T) Given: The temperature dependent of Kp is expressed in the van't Hoff d In K₂_AH* equation dT RT² Assuming that A-H is constant over a temperature range, solve the result in (b) to obtain the expression for the temperature dependence of Kp. (4 points) Given that AH = +57.2 kJ mol-¹ over the temperature range, calculate Kp at 373 K. (2 points) (d) (total 12 points)
[answers Policy: One question per post - questions with sub-parts are
fine, but posts with multiple questions will be closed]
(★Please give complete and correct answers if you choose this
question, otherwise please don't answer it and waste my quota.
Thank you)
5. Dinitrogen tetroxide is 18.46 per cent dissociated at 298 K and 1.00 bar in the equilibrium N2O4(g) 2NO2(g). Assuming that the gases are perfect. (a) calculate Kp and ArG* at 298 K. (4 points) d ln Kp (b) Evaluate (the other form of the van't Hoff equation). (2 points) d (1/T) Given: The temperature dependent of Kp is expressed in the van't Hoff d In K₂_AH* equation dT RT² Assuming that A-H is constant over a temperature range, solve the result in (b) to obtain the expression for the temperature dependence of Kp. (4 points) Given that AH = +57.2 kJ mol-¹ over the temperature range, calculate Kp at 373 K. (2 points) (d) (total 12 points)