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- = Q4: The potential function describing the vibration of the 1H35Cl molecule can be ap- proximated by the Morse functi
Posted: Fri Apr 29, 2022 1:01 pm
by answerhappygod
- Q4 The Potential Function Describing The Vibration Of The 1h35cl Molecule Can Be Ap Proximated By The Morse Functi 1 (135.03 KiB) Viewed 21 times
- = Q4: The potential function describing the vibration of the 1H35Cl molecule can be ap- proximated by the Morse function: V(r – re) = De [e-2a(r-re) – 2e-a(r-re)], where re is the equilibrium internuclear distance (1.27 Å), De is approximately 4.4 eV, and a=1.85x108 cm-1. The rotational constant Be is approximately 10.6 cm-1, the reduced mass u is 1.64x10-24 g. (25 pts) • What are the values in eV of the average potential energy V, the average kinetic energy T, and the total energy E when the internuclear distance is 1.27 Å? The kinetic energy of nuclear motion can be neglected in this problem. • Determine the fundamental vibrational frequency We. • How will the vibration-rotation spectrum for 1H37Cl differ from that of 1H35Cl?